In episode 5 of Windows Games on Linux, I go over Fallout New Vegas and why how to setup your steam to get it working optimally. Overall one of the easiest games to get running on Linux and I feel it is more STABLE than when I played it on Windows!
Configuration Settings:
Change Steam Compatibility Proton Version to 3.16 or above
Launch Options: (Skips Launcher)
DO=(%command%); “${DO[@]/%FalloutNVLauncher.exe/FalloutNV.exe}” .
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